目標乃建立學生在化工熱力學之核心理論基礎，及增進學生在化工程序分析應用及計算之能力。
Course Contents:
Introduction & the Scope of Thermodynamics, Fundamental Concepts of Classical Thermodynamics, First Law of Thermodynamics, Energy Balance for Closed Systems State Functions, Equilibrium, Phase Rule, Reversible Process, Constant-V & Constant-P Processes Mass and Energy Balances for Open Systems, PVT Behavior of Pure Substances, Application of the Virial Equations, Cubic Equations of State, Theorem of Corresponding States Acentric Factor, Generalized Correlations for Gases & Liquids, Heat Effect Basics, Standard Heat of Reaction, Heat of Formation Heat of Combustion, Temperature Dependence, Heat Effects of Industrial Reactions, Statements of the Second Law, Entropy Entropy Changes of an Ideal Gas, Mathematical Statement of the Second Law, Entropy Balance for Open Systems, Third Law of Thermodynamics Thermodynamic Properties of Fluids, Residual functions and properties Two-phase systems, Fundamental Property Relations for Homogeneous Phases, Vapor Liquid Equilibria - Introduction, Phase Rule, Vapor Liquid Equilibria- Qualitative Behavior and Models, Activity Coefficient, Solution Thermodynamics - Fundamental Property Relations.The goal is to establish students' core theoretical foundation in chemical engineering thermodynamics and enhance students' abilities in chemical engineering process analysis, application and calculation.
Course Contents:
Introduction & the Scope of Thermodynamics, Fundamental Concepts of Classical Thermodynamics, First Law of Thermodynamics, Energy Balance for Closed Systems State Functions, Equilibrium, Phase Rule, Reversible Process, Constant-V & Constant-P Processes Mass and Energy Balances for Open Systems, PVT Behavior of Pure Substances, Application of the Virial Equations, Cubic Equations of State, Theorem of Corresponding States Acentric Factor, Generalized Correlations for Gases & Liquids, Heat Effect Basics, Standard Heat of Reaction, Heat of Formation Heat of Combustion, Temperature Dependence, Heat Effects of Industrial Reactions, Statements of the Second Law, Entropy Entropy Changes of an Ideal Gas, Mathematical Statement of the Second Law, Entropy Balance for Open Systems, Third Law of Thermodynamics Thermodynamic Properties of Fluids, Residual functions and properties Two-phase systems , Fundamental Property Relations for Homogeneous Phases, Vapor Liquid Equilibria - Introduction, Phase Rule, Vapor Liquid Equilibria- Qualitative Behavior and Models, Activity Coefficient, Solution Thermodynamics - Fundamental Property Relations.
從古典熱力學之第一、第二定律出發，探討化工程序中熱與功的轉換與限制條件，封閉與開放系統之能量平衡，以及化工程序相關之熱效應，並討論純物質與真實流體混合物之各種熱力性質與關聯方法，建立學生在化工熱力計算及應用之基礎。再介紹流動程序熱力分析及應用，流體混合物熱力性質估算及關聯預測方法，殘餘性質觀念，溶液熱力學理論基礎，氣液相平衡，逸壓及活性係數觀念，狀態方程式應用等，強調熱力學理論在化工程序上之應用。
Starting from the first and second laws of classical thermodynamics, we explore the conversion and limiting conditions of heat and work in chemical processes, the energy balance of closed and open systems, and the thermal effects related to chemical processes, and discuss the various differences between pure substances and real fluid mixtures. Thermodynamic properties and correlation methods establish students’ foundation for thermal calculation and application in chemical engineering. Then introduce the thermodynamic analysis and application of flow procedures, estimation of thermodynamic properties of fluid mixtures and related prediction methods, concepts of residual properties, theoretical basis of solution thermodynamics, gas-liquid phase equilibrium, concepts of escape pressure and activity coefficient, application of equation of state, etc., emphasizing the application of thermodynamic theory in chemical engineering. Program application.
J. M. Smith, H. C. Van Ness, and M. M. Abbott, Introduction to Chemical Engineering Thermodynamics, 7th ed., McGraw Hill (2005).
J. M. Smith, H. C. van Nes, and M. M. Abbott, Introduction to chemical engineering thermodynamics, 7the., McGraw Hill (2005).
| 評分項目 Grading Method | 配分比例 Grading percentage | 說明 Description |
|---|---|---|
| Midterm Exam Midterm Exam midterm exam |
37 | |
| Final Exam Final Exam final exam |
37 | |
| Quizzes Quizzes quizzes |
18 | |
| Homework Assignments/Attendance Homework Assignments/Attendance homework assignments/attendance |
8 |
